(−)-Cytisine and Derivatives: Synthesis, Reactivity, and Applications.Scott E. Allen, Ryan R. Walvoord, Rosaura Padilla-Salinas, and Marisa C. Kozlowski .Aerobic Copper-Catalyzed Organic Reactions.Jin-Ming Gao, Sheng-Xiang Yang, and Jian-Chun Qin .Jaclyn M. Winter, Michio Sato, Satoru Sugimoto, Grace Chiou, Neil K. Garg, Yi Tang, and Kenji Watanabe .Identification and Characterization of the Chaetoviridin and Chaetomugilin Gene Cluster in Chaetomium globosum Reveal Dual Functions of an Iterative Highly-Reducing Polyketide Synthase.Mathieu Achard, Aaron B. Beeler, and John A. Porco, Jr. .Synthesis of Azaphilone-Based Chemical Libraries.Amber D. Somoza, Kuan-Han Lee, Yi-Ming Chiang, Berl R. Oakley, and Clay C. C. Wang .Reengineering an Azaphilone Biosynthesis Pathway in Aspergillus nidulans To Create Lipoxygenase Inhibitors.Shaping Molecular Landscapes: Recent Advances, Opportunities, and Challenges in Dearomatization.Azaphilones from the Marine Sponge-Derived Fungus Penicillium sclerotiorum OUCMDZ-3839.Longlong Li, Dayun Huang, Chengjin Shi, Guobing Yan.2‐Alkynylaryl Aldehydes (Enynals) in Organic Synthesis.Tao A.G. Large, Viswanath Mahadevan, William Keown, T. Daniel P. Stack.Selective oxidation of exogenous substrates by a bis-Cu(III) bis-oxide complex: Mechanism and scope.Mei-Yan Wei, Cui-Fang Wang, Kai-Ling Wang, Pei-Yuan Qian, Chang-Yun Wang, Chang-Lun Shao.Preparation, Structure, and Potent Antifouling Activity of Sclerotioramine Derivatives.Asymmetric Oxidative Dearomatization Reaction.Wangsheng Sun, Guofeng Li, Liang Hong, Rui Wang.Long Han, Wei Zhang, Xiao-Xin Shi, Shu-Li You.Dearomatization of Indoles The mode of incorporation, into lupinine and into sparteine, of cadaverine, intramolecularly doubly labelled with N and with C at the C-atom adjacent to N, was determined by C n.m.r. Of note, site-selective O-methylation of a vinylogous pyridone was used to access the isoquinolin-6(7H)-one core of (+)-8-O-methylsclerotiorinamine. Enzymatic evidence then showed that the three molecules of cadaverine are transformed to the quinolizidine ring via enzyme bound intermediates, without the generation of any free intermediates. Sparteine is a lupin alkaloid containing a tetracyclic bis-quinolizidine ring system derived from three C5 chains of lysine, or more specifically, L-lysine. The A'_piperideine trimer model of sparteine biosynthesis, showing the predicted distribution of label from 1l-l3C,l-lsN]cadaveńne (1, O) and from[2-t4C]- and [6-14C]-A1-piperideine (2 : a,6 : a). Find more information on,Enantioselective syntheses of the azaphilone natural products (+)-sclerotiorin and (+)-8-,Complete experimental procedures and compound characterization data. Please reconnect.Find more information about Crossref citation counts.the Altmetric Attention Score and how the score is calculated.http://pubs.acs.org/page/copyright/permissions.html,https://doi.org/10.1021/acs.orglett.8b02183,https://doi.org/10.1021/acs.orglett.7b02053,https://doi.org/10.1016/j.chempr.2020.06.015,https://doi.org/10.1016/j.ica.2018.11.027,https://doi.org/10.1007/s10126-017-9760-x,https://doi.org/10.1002/9783527698479.ch6,https://doi.org/10.1016/B978-0-08-100023-6.00009-9,https://doi.org/10.1016/j.tet.2014.10.062,https://doi.org/10.1016/j.tet.2014.06.117,https://doi.org/10.1016/j.tetlet.2014.09.028,https://doi.org/10.1016/j.mencom.2013.03.017,https://doi.org/10.1016/j.tetlet.2012.11.084,https://doi.org/10.1016/j.tet.2012.10.051,https://doi.org/10.1016/B978-0-08-095167-6.00311-6,https://doi.org/10.1016/j.tet.2011.07.080. -Alkyl Carbamate.Karuppusamy Sakthivel, Kannupal Srinivasan.Iodine/Water-Mediated Oxidation of Cycloaddition of spiroepoxycyclohexa-2,4-dienones and intramolecular Diels–Alder reaction: a stereoselective entry into tetracyclic core of atisane diterpenoids.Chiral aryl iodide catalysts for the enantioselective synthesis of para-quinols.Sebastián O. Simonetti, Enrique L. Larghi, Andrea B. J. Bracca, Teodoro S. Kaufman.Angular tricyclic benzofurans and related natural products of fungal origin.
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